About 50 results
Open links in new tab
  1. thermodynamics - How can the equation Delta G = -RTln (K_eq) + RTln …

    Dec 29, 2024 · \ceΔG =Geq −Ginitial \ce Δ G = G e q G i n i t i a l We know that the equilibrium condition is where the free energy of the system must be at its minimum. Thus, using this equation we can …

  2. physical chemistry - Gibbs free energy in standard state vs ...

    Mar 24, 2019 · On the one hand: One may describe a chemical reaction with $\Delta G=\Delta G^\circ + RT\ln {Q}$. In equilibrium $\Delta G = 0$ and the equation reads $\Delta G^\circ = -RT \ln {K}$. On …

  3. Derivation of relationship between Gibbs free energy and ...

    Why is $\\Delta G = -nFE$? I don't understand what the motivation is behind this definition. Was it derived or just given? The textbook provides no justification for this equation. In fact, much of...

  4. Gibbs free energy ΔG=ΔG°+RTln(Kp) different expressions for ΔG

    Jan 20, 2019 · If I understand it correctly, the ΔG in this equation gives the "distance" in Gibbs free energy of a chemical system at a particular moment in a reaction (encoded by the Kp) to the gibbs …

  5. physical chemistry - What is the difference between ΔG and ΔrG ...

    May 3, 2016 · Unfortunately, the notation $\Delta G$ is often loosely used and treated as being synonymous with $\Delta_\mathrm {r}G$. You will therefore see people give $\Delta G$ units of …

  6. thermodynamics - What's the difference between ΔG° and ΔG ...

    Jun 27, 2019 · 10 In biochemistry contexts, one often sees $\Delta G^ {\circ\prime}$ ("delta G naught prime"), rather than the normal standard free energy change $\Delta G^ {\circ}$ ("delta G naught"). …

  7. physical chemistry - At nonstandard conditions, how does delta G …

    Oct 6, 2024 · The equation ΔG = ΔH − TΔS Δ G = Δ H T Δ S is used as I described but with ΔG =6300 Jmol−1 Δ G = 6300 J m o l 1, to yield D as the answer. I'm pretty sure my confusion arises from the …

  8. Is ΔS of a system related to temperature and change in enthalpy?

    Jun 8, 2016 · If the system experiences a change at constant pressure, the change in enthalpy of the system $\Delta H_ {system}$ is equal to the heat Q transferred from the surroundings to the system. …

  9. thermodynamics - Chemistry Stack Exchange

    Nov 28, 2018 · When you are talking about the change in a state function like G, it is important to precisely define the initial and final thermodynamic equilibrium states of the system you are …

  10. How to determine the value for n in the Gibbs free energy and redox ...

    Apr 25, 2015 · $n$ does, and hence $\Delta G = -nFE_\mathrm {cell}$ does. Your choice of the full cell reaction determines the value of $n$ you work with. The best definition of $n$ is the stoichiometric …