
thermodynamics - How can the equation Delta G = -RTln (K_eq) + RTln …
Dec 29, 2024 · \ceΔG =Geq −Ginitial \ce Δ G = G e q G i n i t i a l We know that the equilibrium condition is where the free energy of the system must be at its minimum. Thus, using this equation we can …
physical chemistry - Gibbs free energy in standard state vs ...
Mar 24, 2019 · On the one hand: One may describe a chemical reaction with $\Delta G=\Delta G^\circ + RT\ln {Q}$. In equilibrium $\Delta G = 0$ and the equation reads $\Delta G^\circ = -RT \ln {K}$. On …
Derivation of relationship between Gibbs free energy and ...
Why is $\\Delta G = -nFE$? I don't understand what the motivation is behind this definition. Was it derived or just given? The textbook provides no justification for this equation. In fact, much of...
Gibbs free energy ΔG=ΔG°+RTln(Kp) different expressions for ΔG
Jan 20, 2019 · If I understand it correctly, the ΔG in this equation gives the "distance" in Gibbs free energy of a chemical system at a particular moment in a reaction (encoded by the Kp) to the gibbs …
physical chemistry - What is the difference between ΔG and ΔrG ...
May 3, 2016 · Unfortunately, the notation $\Delta G$ is often loosely used and treated as being synonymous with $\Delta_\mathrm {r}G$. You will therefore see people give $\Delta G$ units of …
thermodynamics - What's the difference between ΔG° and ΔG ...
Jun 27, 2019 · 10 In biochemistry contexts, one often sees $\Delta G^ {\circ\prime}$ ("delta G naught prime"), rather than the normal standard free energy change $\Delta G^ {\circ}$ ("delta G naught"). …
physical chemistry - At nonstandard conditions, how does delta G …
Oct 6, 2024 · The equation ΔG = ΔH − TΔS Δ G = Δ H T Δ S is used as I described but with ΔG =6300 Jmol−1 Δ G = 6300 J m o l 1, to yield D as the answer. I'm pretty sure my confusion arises from the …
Is ΔS of a system related to temperature and change in enthalpy?
Jun 8, 2016 · If the system experiences a change at constant pressure, the change in enthalpy of the system $\Delta H_ {system}$ is equal to the heat Q transferred from the surroundings to the system. …
thermodynamics - Chemistry Stack Exchange
Nov 28, 2018 · When you are talking about the change in a state function like G, it is important to precisely define the initial and final thermodynamic equilibrium states of the system you are …
How to determine the value for n in the Gibbs free energy and redox ...
Apr 25, 2015 · $n$ does, and hence $\Delta G = -nFE_\mathrm {cell}$ does. Your choice of the full cell reaction determines the value of $n$ you work with. The best definition of $n$ is the stoichiometric …